Associate Professor of Physical Chemistry, Department Chair
On Faculty since 1999
Ph.D. Physical Chemistry, Univ. of Minnesota, 1997
B.S. Chemistry, Wheaton College, 1991
About Peter Walhout
Dr. Walhout's current reseach interest lies in the area of polyelectrolyte multilayer thin films (PMLs). These films are created by a relatively new self-assembly technique whereby alternating layers of positively and negatively charged polyelectrolytes are deposited onto a substrate from solution. Many variations on this versatile synthetic technique can be employed, including adsorbing charged small molecules such as dyes into the thin film structure or creating discrete layers of non-charged conducting polymers by assembling a layer of the charged monomers followed by in situ polymerization.
Several projects related to fundamental properties of PMLs are underway. One project involves investigating whether a glass transition temperature can be found for typical PMLs using phase-modulated ellipsometry to track thickness changes as a function of temperature. Other projects relate to measuring the rotational and translational diffusion of small charged molecules embedded in the thin films using FRAP methods (fluorescence recovery after photobleaching). These diffusion measurements will be useful for PML applications that involve small molecules, but they are also useful on a more fundamental level as a probe of the polymer dynamics in the thin film. Lastly, a project has just started in which electron transfer dynamics will be examined between donor and acceptor layers within a PML. This study will be undertaken using transient absorption and time-correlated single photon counting techniques employing a Ti:sapphire ultrafast laser. This research combines Dr. Walhout's interest in spectroscopy and polymers. His ultrafast thesis work at Minnesota under Paul Barbara was titled "Ultrafast Studies of Radical Anions in Solution." This was followed a post-doctoral appointment at the University of Wisconsin working with Mark Ediger in the area of polymer dynamics.
Dr. Walhout married his wife Jenna in 1992 and they now have four children. Both are Wheaton alums and enjoy being back in the Chicagoland area where they are close to their kids' four grandparents and 2 great-grandparents. They are active in their local church where Dr. Walhout sings in the choir. He also enjoys watching and playing many sports and is happy to be close to the Chicago sports teams again after too long an exposure to Vikings and Packers fans.
- General Chemistry
- Physical Chemistry I and II
- Methods in Physical Chemistry
Membership in Professional Societies
- American Chemical Society
- Midwest Association of Chemistry Teachers at Liberal Arts Colleges (MACTLAC)
Selected Papers Published and/or Presented
(student coauthors in bold)
Burden, D.L., Walhout, P.K., Elliott, J.T, Chandler, E.L., Scharf, R.G., Culbertson, M.J., Stults, D.A., Rupp, E.L., Poppen, S.D., “Measuring Diffusion in Nanoscale Environments with Single-Molecule Confocal Fluorescence Microscopy,” Spectroscopy Letters, in press.
Yokoyama, K., Silva, C., Son, D., Walhout, P.K., Barbara, P.F., 1998. Detailed Investigation of the Femtosecond Pump-Probe Spectroscopy of the Hydrated Electron. J. Phys. Chem. A 102: 6957.
Silva, C., Walhout, P.K., Reid, P.J., Barbara, P.F. 1998. Detailed Investigations of the Pump-Probe Spectroscopy of the Equilibrated Solvated Electron in Alcohols. J. Phys. Chem. A 102: 5701.
Silva, C., Walhout, P.K., Yokoyama, K., Barbara, P.F., 1998. Femtosecond Solvation Dynamics of the Hydrated Electron. Phys. Rev. Lett. 80: 1086.
Walhout, P.K., Silva, C., Barbara, P.F., 1996. Ultrafast Study of the Photodissociation and Recombination of Aqueous O3-. J. Phys. Chem. 100: 5188.
Walhout, P.K., Alfano, J.C., Thakur, K.A.M., Barbara, P.F.J. 1995. Ultrafast Experiments on the Photodissociation, Recombination, and Vibrational Relaxation of I2-: Role of Solvent-Induced Solute Charge Flow. J. Phys. Chem. 99: 7568.
Walhout, P.K., Alfano, J.C., Kimura, Y., Silva, C., Reid, P.J., Barbara, P.F., 1995. Direct pump/probe spectroscopy of the near-IR band of the solvated electron in alcohols. Chem. Phys. Lett. 232: 135.
Reid, P.J., Silva, C, Walhout, P.K., Barbara, P.F., 1994. Femtosecond absorption anisotropy of the aqueous solvated electron. Chem. Phys. Lett. 228: 658.
Kimura, Y, Alfano, J.C., Walhout, P.K., Barbara, P.F., 1994. Ultrafast Transient-Absorption Spectroscopy of the Solvated Electron in Water. J. Phys. Chem. 98: 3450.
Alfano, J.C., Kimura, Y., Walhout, P.K., Barbara, P.F., 1993. Photodissociation and vibrational relaxation of I2- in water, ethanol, and ethanol-d1. Chem. Phys. 175: 147.
Alfano, J.C., Walhout, P.K., Kimura, Y., Barbara, P.F., 1993. Ultrafast transient-absorption spectroscopy of the aqueous solvated electron. J. Chem. Phys. 98: 5996.